What is silane crosslinking?

Silane crosslinking is a chemical crosslinking process for Thermoplastics and elastomers, in which so-called silaneCopolymers crosslink under the influence of moisture. The process is used in particular for thermoplastic polyethylene (PE), turning it into a non-genuine elastomer, e.g. for pipes or cable sheathing. It is also used for room temperature crosslinking (RTV) silicones and other silane-modified elastomers such as EPDM with silane group or TPO-Si.

 

How does silane crosslinking work?

During silane crosslinking, reactive silane groups are chemically bonded to a Polymer attached. These groups react later - after the Extrusion or shaping - under the influence of water (also as vapour or ambient humidity) and a catalyst (usually an organotin). The result is cross-linking with improved mechanical and thermal properties.

 

Advantages:

  • Can be processed at room temperature or slightly higher temperatures
  • Simple post-crosslinking possible, partly due to humidity

 

Disadvantages:

  • Can only be used for certain elastomers
  • Poorer dynamic properties
  • Silane-modified base material is often more expensive

 

Typical applications:

  • Silane-crosslinked polyethylene as a non-genuine elastomer for sanitary, heating and gas pipes
  • RTV silicone insulation in the electrical sector